Semi-Empirical Oscillator Strengths and Lifetimes for the P II Spectrum
DOI:
https://doi.org/10.22481/exon.v12i1.20506Keywords:
energy levels, P II spectrum, atomic transitions, oscillator strengths, lifetimesAbstract
In this work, the values of oscillator strengths and lifetimes in the spectrum P II are calculated. The semi-empirical method of using the values of experimental wavelengths and energy levels according to previous spectral analysis and data compilation work and are now used as the basis for calculations of fitting of the electrostatic parameters using Cowan codes in the energy matrix that represents the Hamiltonian of the ion. A Hartree-Fock relativistic (HFR) multiconfigurational approach is used and the parameters are now adjusted being optimized by a least-squares procedure, in order to improve the adjustment to experimental energy levels by the least squares method in both parities. The method produces simulated values that are difficult to obtain experimentally of oscillator strengths (gf) for known spectral lines and that in agreement with intensity observations, and lifetimes for energy levels, that are closer to the experimental ones.
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References
Martin, W.C., Zalubas, R. and Musgrove, A. (1985) J. Phys. Chem. Ref. Data Vol. 14 No. 3, 796-797.
Geuter, P. (1907) H andbuch der Spectroscopie, Vol. 6. Zeits. f. Wiss. Photographie, 5, 33-60.
Bowen, I.S. and Millikan , R.A. (1925) The Series Spectra of Two-Valence-Electron Atoms of Phosphorus (PIV), Sulphur (SV), and Chlorine (ClVI). Phys. Rev. 25, 591-599.
Bowen, I.S. (1927) Series Spectra of Ionized Phosphorus, P II. Phys. Rev. 29, 510–512.
Robinson, H.A. (1936) The Spectra of Phosphorus Part I. The Spectra of Neutral and Singly Ionized Phosphorus. Phys. Rev. 49, 297 305.
Robinson, H.A. (1937) The Spectra of Phosphorus Part II: The Spectra of Doubly, Triply and Quadruply Ionized Phosphorus (P III, P IV, Additions and Corrections to P II. Phys. Rev. 51, 726–734.
Martin, W.C. (1959) Atomic Energy Levels and Spectra of Neutral and Singly Ionized Phosphorus (P I and P II), J. Opt. Soc. Am. 49, 1071–1085.
Li, H.. and Andrew, K.L. (1971) First Spark Spectrum of Arsenic. J. Opt. Soc. Am. 61, 96-109.
Li, H.. and Andrew, K.L. (1972) Need of LS-Dependent Energy Parameters in the Second Spectra of the Fifth_Group Elements. J. Opt. Soc. Am. 62, 1476–1482.
Li, H. (1972) Zeeman Effect of P II. J. Opt. Soc. Am. 62, 1483–1488.
Svendenius, N., Magnusson, C.E. and Zetterberg, P.O. (1983) The Spectrum of Singly Ionized Phosphorus, P II. Phys. Scr. 27, 339–363.
R. D. Cowan, R.D. (1981) The theory of atomic structure and spectra. Berkeley CA: University of California Press.
Fawcett, B.C. (1991) The Effects of Relativity in Atoms, Molecules, and the Solid State - "On the Accuracy of Oscillator Strengths" Springer US, Plenum Press, New York, 45-54.
Owens, J.C. (1967) Optical Refractive Index of Air: Dependence on Pressure, Temperature and Composition. Applied Optics 6, 51-59.
Aller, L.H. Distribution of the chemical elements, Moscow:Foreign Literature Press, 1963.
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