Evaluation of catalytic precursors of radical hydrogen peroxide decomposition

Naiara Miotto Menino; Raquel Vera Zamadei; Carolina Elisa Demaman Oro; Luciana Dornelles Venquiaruto; Rogério Marcos Dallago; Marcelo Luis Mignoni

doi:10.22481/exon.v12i2.20598

Authors

Naiara Miotto Menino Instituto Federal de Educação, Ciência e Tecnologia do Rio Grande do Sul
Raquel Vera Zamadei Department of Food and Chemical Engineering, URI
Carolina Elisa Demaman Oro Department of Food and Chemical Engineering, URI
Luciana Dornelles Venquiaruto Department of Food and Chemical Engineering, URI
Rogério Marcos Dallago Department of Food and Chemical Engineering, URI
Marcelo Luis Mignoni Department of Food and Chemical Engineering, URI

DOI:

https://doi.org/10.22481/exon.v12i2.20598

Keywords:

H2O2, iodide, chloride, bromide, methylene blue, gasometry

Abstract

The decomposition of radical hydrogen peroxide has aroused great interest from the scientific community due to the numerous possible applications, mainly concerning to the treatment of effluents. However, it is important to find new precursors for radical H2O2 decomposition. The potential of halogens (non-metals) iodine, chlorine, and bromine, in the form of iodide (I-), chloride (Cl-), and bromide (Br-) ions, as catalytic precursors of the radical decomposition of the hydrogen peroxide, was evaluated. A solution of methylene blue was used as a model molecule of a contaminant to prove the radical mechanism from the effect of the organic compound on the volume of O2 generated. The results of the experiments showed that iodide at acidic pH can act as a catalyst for the radical H2O2 decomposition mechanism in a spontaneous redox process (positive ΔE°). In contrast, the chloride ion showed slow decomposition kinetics of hydrogen peroxide (more than 72h), and the bromide ion was not characterized as a catalyst for H2O2 decomposition. Finally, a reduction in the production of O2 is observed for the reaction with iodide ion in the presence of the organic contaminant in relation to the experiment with only water and H2O2.

Downloads

Download data is not yet available.

References

B. Ozbey Unal, Z. Bilici, N. Ugur, Z. Isik, E. Harputlu, N. Dizge, K. Ocakoglu, Adsorption and Fenton oxidation of azo dyes by magnetite nanoparticles deposited on a glass substrate, J. Water Process Eng. 32 (2019) 100897. doi:10.1016/j.jwpe.2019.100897.

F. Liu, J. Zhang, Y. Liu, S. Niu, J. Wan, Electrochemical determination of hydrogen peroxide on a gold nanoparticle–nitrogen-doped graphene glassy carbon electrode, Instrum. Sci. Technol. 46 (2018) 555–566. doi:10.1080/10739149.2017.1410488.

C. Seo, J. Shin, M. Lee, W. Lee, H. Yoom, H. Son, S. Jang, Y. Lee, Elimination efficiency of organic UV filters during ozonation and UV/H2O2 treatment of drinking water and wastewater effluent, Chemosphere. 230 (2019) 248–257. doi:10.1016/j.chemosphere.2019.05.028.

J. Zhu, X. Xiao, K. Zheng, F. Li, G. Ma, H.C. Yao, X. Wang, Y. Chen, KOH-treated reduced graphene oxide: 100% selectivity for H2O2 electroproduction, Carbon N. Y. 153 (2019) 6–11. doi:10.1016/j.carbon.2019.07.009.

R. Goyal, O. Singh, A. Agrawal, C. Samanta, B. Sarkar, Advantages and limitations of catalytic oxidation with hydrogen peroxide: from bulk chemicals to lab scale process, Catal. Rev. - Sci. Eng. 00 (2020) 1–57. doi:10.1080/01614940.2020.1796190.

E. Neyens, J. Baeyens, A review of classic Fenton’s peroxidation as an advanced oxidation technique, J. Hazard. Mater. 98 (2003) 33–50. doi:10.1016/S0304-3894(02)00282-0.

R. Ciriminna, L. Albanese, F. Meneguzzo, M. Pagliaro, Hydrogen Peroxide: A Key Chemical for Today’s Sustainable Development, ChemSusChem. 9 (2016) 3374–3381. doi:10.1002/cssc.201600895.

G. Subramanian, G. Madras, Potentiation of hydrogen peroxide mediated water decontamination using thioglycolic acid, J. Environ. Chem. Eng. 6 (2018) 2200–2205. doi:10.1016/j.jece.2018.03.020.

A. Devard, P. Brussino, F.A. Marchesini, M.A. Ulla, Cu(5%)/Al2O3 catalytic performance on the phenol wet oxidation with H2O2: Influence of the calcination temperature, J. Environ. Chem. Eng. 7 (2019). doi:10.1016/j.jece.2019.103201.

I.L. de Mattos, K.A. Shiraishi, A.D. Braz, J.R. Fernandes, Peróxido de hidrogênio: Importância e Determinação, Quim. Nova. 26 (2003) 373–380.

M. Verma, A.K. Haritash, Degradation of amoxicillin by Fenton and Fenton-integrated hybrid oxidation processes, J. Environ. Chem. Eng. 7 (2019) 102886. doi:10.1016/j.jece.2019.102886.

M. hui Zhang, H. Dong, L. Zhao, D. xi Wang, D. Meng, A review on Fenton process for organic wastewater treatment based on optimization perspective, Sci. Total Environ. 670 (2019) 110– 121. doi:10.1016/j.scitotenv.2019.03.180.

Y. Zhu, R. Zhu, Y. Xi, J. Zhu, G. Zhu, H. He, Strategies for enhancing the heterogeneous fenton catalytic reactivity: A review, Appl. Catal. B Environ. 255 (2019). doi:10.1016/j.apcatb.2019.05.041.

M.M. Bello, A.A. Abdul Raman, A. Asghar, A review on approaches for addressing the limitations of Fenton oxidation for recalcitrant wastewater treatment, Process Saf. Environ. Prot. 126 (2019) 119–140. doi:10.1016/j.psep.2019.03.028.

Y. Pan, Y. Zhang, M. Zhou, J. Cai, Y. Tian, Enhanced removal of antibiotics from secondary wastewater effluents by novel UV/pre-magnetized Fe0/H2O2 process, Water Res. 153 (2019) 144–159. doi:10.1016/j.watres.2018.12.063.

M.A. Hasan, M.I. Zaki, L. Pasupulety, K. Kumari, Promotion of the hydrogen peroxide decomposition activity of manganese oxide catalysts, Appl. Catal. A Gen. 181 (1999) 171–179. doi:10.1016/S0926-860X(98)00430-X.

N. de O. Dos Santos, L. Teixeira, Accelerated reoxygenation of water bodies using hydrogen peroxide, Int. J. Environ. Stud. 76 (2019) 558–570. doi:10.1080/00207233.2018.1494929.

J. An, N. Li, Q. Zhao, Y. Qiao, S. Wang, C. Liao, L. Zhou, T. Li, X. Wang, Y. Feng, Highly efficient electro-generation of H2O2 by adjusting liquid-gas-solid three phase interfaces of porous carbonaceous cathode during oxygen reduction reaction, Water Res. 164 (2019) 114933. doi:10.1016/j.watres.2019.114933.

G. Sönmez, T. Bahadır, M. Işık, Removal of selected pharmaceuticals from tap water by the Fenton process, Int. J. Environ. Anal. Chem. 00 (2020) 1–13. doi:10.1080/03067319.2020.1776860.

A. Kumar, A. Rana, G. Sharma, M. Naushad, P. Dhiman, A. Kumari, F.J. Stadler, Recent advances in nano-Fenton catalytic degradation of emerging pharmaceutical contaminants, J. Mol. Liq. 290 (2019) 111177. doi:10.1016/j.molliq.2019.111177.

A. Babuponnusami, K. Muthukumar, A review on Fenton and improvements to the Fenton process for wastewater treatment, J. Environ. Chem. Eng. 2 (2014) 557–572. doi:10.1016/j.jece.2013.10.011.

J.N. Göde, D. Hoefling Souza, V. Trevisan, E. Skoronski, Application of the Fenton and Fenton-like processes in the landfill leachate tertiary treatment, J. Environ. Chem. Eng. 7 (2019). doi:10.1016/j.jece.2019.103352.

P.W. Atkins, L. Jones, Princípios de química: questionando a vida moderna e o meio ambiente, 5th ed., Bookman, Porto Alegre, 2013.

A.M. Shams El Din, R.A. Mohammed, Kinetics of the reaction between hydrogen peroxide and hypochlorite, Desalination. 115 (1998) 145–153. doi:10.1016/S0011-9164(98)00034-4.

S. Siddiqui, M. Keswani, B. Brooks, A. Fuerst, S. Raghavan, A study of hydrogen peroxide decomposition in ammonia-peroxide mixtures (APM), Microelectron. Eng. 102 (2013) 68–73. doi:10.1016/j.mee.2012.04.003.

L.C.A. Oliveira, T.C. Ramalho, E.F. Souza, M. Gonçalves, D.Q.L. Oliveira, M.C. Pereira, J.D. Fabris, Catalytic properties of goethite prepared in the presence of Nb on oxidation reactions in water: Computational and experimental studies, Appl. Catal. B Environ. 83 (2008) 169–176. doi:10.1016/j.apcatb.2008.01.038.

X. Tao, C. Yang, Z. Wei, L. Huang, J. Chen, W. Cong, R. Xie, D. Xu, Synergy between Fenton process and DBD for methyl orange degradation, Mater. Res. Bull. 120 (2019) 110581. doi:10.1016/j.materresbull.2019.110581.

B. Shen, C. Dong, J. Ji, M. Xing, J. Zhang, Efficient Fe(III)/Fe(II) cycling triggered by MoO2 in Fenton reaction for the degradation of dye molecules and the reduction of Cr(VI), Chinese Chem. Lett. 30 (2019) 2205–2210. doi:10.1016/j.cclet.2019.09.052.

M. Malakootian, A. Nasiri, M. Khatami, H. Mahdizadeh, P. Karimi, M. Ahmadian, N. Asadzadeh, M.R. Heidari, Experimental data on the removal of phenol by electro-H2O2 in presence of UV with response surface methodology, MethodsX. 6 (2019) 1188–1193. doi:10.1016/j.mex.2019.05.004.

D. Moretto, Avaliação da remoção de pigmentação de calda de indústria de balas utilizando peróxido de hidrogênio promovido com íon hidroxila, Universidade Regional Integrada do Alto Uruguai e das Missões, URI Erechim, 2011.

N. Wang, T. Zheng, G. Zhang, P. Wang, A review on Fenton-like processes for organic wastewater treatment, J. Environ. Chem. Eng. 4 (2016) 762–787. doi:10.1016/j.jece.2015.12.016.

N. Ertugay, F.N. Acar, Removal of COD and color from Direct Blue 71 azo dye wastewater by Fenton’s oxidation: Kinetic study, Arab. J. Chem. 10 (2017) S1158–S1163. doi:10.1016/j.arabjc.2013.02.009.

A. Cruz-Rizo, S. Gutiérrez-Granados, R. Salazar, J.M. Peralta-Hernández, Application of electro-Fenton/BDD process for treating tannery wastewaters with industrial dyes, Sep. Purif. Technol. 172 (2017) 296–302. doi:10.1016/j.seppur.2016.08.029.

N.C. Fernandes, L.B. Brito, G.G. Costa, S.F. Taveira, M.S.S. Cunha-Filho, G.A.R. Oliveira, R.N. Marreto, Removal of azo dye using Fenton and Fenton-like processes: Evaluation of process factors by Box–Behnken design and ecotoxicity tests, Chem. Biol. Interact. 291 (2018) 47–54. doi:10.1016/j.cbi.2018.06.003.

J.D. Lee, Química inorgânica não tão concisa, 5th ed., Edgard Blücher, São Paulo, 1999.